(4E)-N-[(2-Chlorophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine
نویسندگان
چکیده
In the title compound, C(26)H(27)ClN(2)O, the piperidine ring has a chair conformation and all of the ring substituents at Csp(3) atoms occupy equatorial positions. The dihedral angle formed between the phenyl rings is 48.11 (9)°. The chloro-benzene ring occupies a position orthogonal to the meth-oxy(methyl-idene)amine residue [N-O-C-C torsion angle = -87.90 (15)°]. The conformation about the imine C=N bond [1.278 (2) Å] is E, and the chloro substituent is anti to the piperidine N atom. Helical supra-molecular chains along [010] are sustained by C-H⋯π inter-actions in the crystal packing.
منابع مشابه
(4E)-N-[(2-Bromophenyl)methoxy]-1,3-dimethyl-2,6-diphenylpiperidin-4-imine
In the title compound, C(26)H(27)BrN(2)O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bis-ectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromo-benzene ring. The latter ...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012